dc.contributor.author |
Fabiane, M. |
|
dc.contributor.author |
Madito, M. J. |
|
dc.contributor.author |
Bello, A. |
|
dc.contributor.author |
Manyala, N. |
|
dc.date.accessioned |
2017-02-01T09:11:12Z |
|
dc.date.available |
2017-02-01T09:11:12Z |
|
dc.date.issued |
2017 |
|
dc.identifier.issn |
1097-4555 |
|
dc.identifier.uri |
http://dx.doi.org/10.1002/jrs.5094 |
|
dc.identifier.uri |
http://repository.tml.nul.ls/handle/20.500.14155/1151 |
|
dc.description.abstract |
We report on the effect of temperature on the growth of bilayer graphene on a copper foil under atmospheric pressure chemical
vapour deposition (AP-CVD). Before characterization of the AP-CVD bilayer graphene, a high-quality graphene flake was obtained
from the Kish bulk graphite by micro-mechanical exfoliation and characterized by using Raman spectroscopy and imaging. The
Raman data of the exfoliated, high-quality graphene flake show monolayer and bilayer graphenes and were compared with
the Raman data of AP-CVD graphene. Raman spectroscopy of AP-CVD graphene shows bilayer films that exhibit predominantly
Bernal stacking with an I2D/IG ratio of ~1. At low growth temperature (~780 °C), Raman disorder-related peak intensity in the
AP-CVD graphene is high and decreases with an increase in growth temperature to the lowest disorder intensity at ~973 °C.
The selected area electron diffraction and atomic force microscopy average step height analysis showed the thickness of the bilayer
graphene. The AP-CVD graphene is uniform at low growth temperatures (~780 °C) with a high disorder and becomes nonuniform
at high growth temperatures (~867–973 °C) with a very low disorder as bilayer graphene evolves to form islands with
an average lateral size of <10 μm. Competition between carbon adatoms supply through dehydrogenation of the CHx species,
mobility and desorption rate of the carbon-adatom species for nucleation of the bilayer graphene as a function of temperature
is elucidated. This study provides further insight into the growth mechanisms of bilayer graphene by AP-CVD on Cu. |
en_ZA |
dc.language.iso |
en |
en_ZA |
dc.rights |
Copyright © 2017 John Wiley & Sons, Ltd. |
en_ZA |
dc.source |
Journal of Raman Spectroscopy |
en_ZA |
dc.subject |
graphene |
en_ZA |
dc.subject |
AP-CVD |
en_ZA |
dc.subject |
copper foil |
en_ZA |
dc.subject |
Bernal-stacked bilayer |
en_ZA |
dc.subject |
exfoliated graphene |
en_ZA |
dc.title |
Raman spectroscopy and imaging of Bernalstacked bilayer graphene synthesized on copper foil by chemical vapour deposition: growth dependence on temperature |
en_ZA |
dc.type |
Article |
en_ZA |