Synthesis and characterization of Y3+-doped TiO2 nanocomposites for photocatalytic applications

Abstract

The TiO2·[Y2O3]x (x = 0.1–0.4) nanocomposites (NCs) with an average particle size of 74 nm were prepared by the method of chemical co-precipitation followed by hydrolysis (CPH). Their visible light photocatalytic activity was investigated for the degradation of congo red (CR) dye. All NCs showed improved degradation as compared to the polycrystalline samples of similar compositions prepared by the solid-state reaction (SSR) route (average particle size of a few micrometers), as well as to the pure TiO2. The better photocatalytic activity of the NCs was attributed to their smaller particle size. Another comparison of the results with those obtained with Zn2+/Fe3+ ions co-doped TiO2 NCs, under similar experimental conditions, revealed that in the Y3+-doped NCs, particle size might not be the only factor responsible for the improved photocatalytic properties. It was concluded that the Y3+ ion-mediated suppression of the unwanted e−/h+ recombination could be the possible factor leading to additional enhancement.